Bisphenol A-bis(diphenyl phosphate) (BDP) (CAS No. 5945-33-5):
1. Basic Information
- Chemical Name:
- Bisphenol A bis(diphenyl phosphate) (IUPAC)
- Abbreviations: BDP or BAPP
- CAS Number: 5945-33-5
- Molecular Formula: C₃₉H₃₄O₈P₂
- Molecular Weight: ~692 g/mol
- Appearance: White to light yellow powder or flakes
2. Applications
BDP is a highly effective organophosphate flame retardant (OPFR) widely used in:
(1) Electronics & Electrical Equipment
- Printed Circuit Boards (PCBs): Flame retardant for epoxy resin substrates (meets UL 94 V-0 standard).
- Electronic Housings: Laptop/phone casings (PC/ABS blends), connectors. Wire & Cable Insulation: Prevents flame propagation in PVC/PE coatings.
(2) Automotive Industry
- Interior Components: Dashboard panels, seat foams (complies with FMVSS 302).
- EV Battery Systems: Battery casings and high-voltage components.
(3) Construction Materials
- Fireproof Coatings: For steel structures and tunnel linings.
- Thermal Insulation Foams: Polyurethane (PU) and polystyrene (EPS) foams.
(4) Aerospace & Transportation
- Aircraft seat cushions and interior panels (FAR 25.853 compliant).
3. Technical Advantages
- Excellent Compatibility: Disperses well in polymers (PC, ABS, PET, etc.).
- Low Volatility/Migration: Enhances product longevity.
- Dual-Phase Flame Retardancy:
- Gas Phase: Releases PO· radicals to quench flames.
- Condensed Phase: Promotes char formation as a thermal barrier.
4. Safety & Regulatory Notes
- Toxicity Concerns:
- Potential degradation to diphenyl phosphate (DPP) – an endocrine disruptor.
- May emit phenols/phosphorus oxides at >300°C.
- Regulatory Status:
- EU: Under REACH evaluation; restricted in some applications.
- China: Permitted but monitored under GB standards.
- Alternatives:
- Halogen-free options (e.g., aluminum diethylphosphinate, RDP).
5. Frequently Asked Questions
Q1: Is CAS 5945-33-5 identical to 181028-79-5?
- Likely the same compound with minor registration variations (e.g., isomerism/purity). Confirm with supplier data.
Q2: What is BDP’s thermal stability?
- Stable up to ~300°C; avoid higher temperatures to prevent decomposition.
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